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Phys. Rev. Lett. 100, 117801 (2008) [4 pages]

In Situ Observation of Fringing-Field-Induced Phase Separation in a Liquid-Crystal–Monomer Mixture

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Hongwen Ren and Shin-Tson Wu
College of Optics and Photonics, University of Central Florida, Orlando, Florida 32816, USA

Yi-Hsin Lin
Department of Photonics, Institute of Electro-Optical Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan

Received 31 July 2007; published 20 March 2008

Fringing-field-induced phase separation dynamics in liquid-crystal–(LC-)monomer mixtures is investigated via a microscope. At a low LC concentration, the fringing field converts the randomly dispersed LC droplets to an ordered droplet array, while at a high LC concentration the fringing field converts the amorphous LC-monomer system to a composite film. Because the LC and monomer are immiscible, the converted morphologies are stable even after the voltage is removed. Using the fringing field-induced phase separation, it is possible to prepare different polymer-dispersed LC morphologies.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.100.117801
DOI:
10.1103/PhysRevLett.100.117801
PACS:
61.30.−v, 42.70.Df, 77.84.Nh