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Phys. Rev. Lett. 100, 195701 (2008) [4 pages]

Numerical Investigation of Glassy Dynamics in Low-Density Systems

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Emanuela Zaccarelli1, Stefan Andreev2, Francesco Sciortino1, and David R. Reichman2
1Dipartimento di Fisica and CNR-INFM-SOFT, Università di Roma La Sapienza, Piazzale A. Moro 2, 00185 Roma, Italy
2Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA

Received 1 November 2007; revised 14 April 2008; published 12 May 2008

Vitrification in colloidal systems typically occurs at high densities driven by sharply varying, short-ranged interactions. The possibility of glassy behavior arising from smoothly varying, long-ranged particle interactions has received relatively little attention. Here we investigate the behavior of screened charged particles, and explicitly demonstrate that these systems exhibit glassy properties in the regime of low temperature and low density. Properties close to this low-density (Wigner) glass transition share many features with their hard-sphere counterparts, but differ in quantitative aspects that may be accounted for via microscopic theoretical considerations.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.100.195701
DOI:
10.1103/PhysRevLett.100.195701
PACS:
64.70.P−, 61.20.Lc, 64.70.Q−, 82.70.Dd