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Phys. Rev. Lett. 100, 027604 (2008) [4 pages]

Nonlinear Piezoelectricity in Epitaxial Ferroelectrics at High Electric Fields

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Alexei Grigoriev1, Rebecca Sichel1, Ho Nyung Lee2, Eric C. Landahl3, Bernhard Adams3, Eric M. Dufresne3, and Paul G. Evans1
1Department of Materials Science and Engineering, University of Wisconsin, Madison, Wisconsin 53706, USA
2Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
3Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA

Received 28 July 2007; published 18 January 2008

Nonlinear effects in the coupling of polarization with elastic strain have been predicted to occur in ferroelectric materials subjected to high electric fields. Such predictions are tested here for a PbZr0.2Ti0.8O3 ferroelectric thin film at electric fields in the range of several hundred MV/m and strains reaching up to 2.7%. The piezoelectric strain exceeds predictions based on constant piezoelectric coefficients at electric fields from approximately 200 to 400  MV/m, which is consistent with a nonlinear effect predicted to occur at corresponding piezoelectric distortions.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.100.027604
DOI:
10.1103/PhysRevLett.100.027604
PACS:
77.65.−j, 68.37.Yz, 77.84.Dy, 78.47.−p