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Phys. Rev. Lett. 100, 214101 (2008) [4 pages]

Clusters and Switchers in Globally Coupled Photochemical Oscillators

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Annette F. Taylor*, Panagiotis Kapetanopoulos, and Benjamin J. Whitaker
School of Chemistry, University of Leeds, Leeds LS2 9JT, United Kingdom

Rita Toth and Larry Bull
School of Computer Science, University of the West of England, Bristol BS16 1QY, United Kingdom

Mark R. Tinsley
Department of Chemistry, University of West Virginia, Morgantown, West Virginia 26506-6045, USA

Received 18 January 2008; published 30 May 2008

We experimentally investigate the transition to synchronization in a population of photochemical oscillators with weak global coupling. Above a critical coupling strength the oscillators join a one-phase group or two-phase clusters. The number of oscillators in each cluster depends on the initial phase distribution, and irregular switching of oscillators between clusters is observed. The fully synchronized state emerges above a second critical coupling strength. In agreement with earlier theory, the experiments demonstrate the importance of population heterogeneity in cluster multistability.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.100.214101
DOI:
10.1103/PhysRevLett.100.214101
PACS:
05.45.Xt

*A.F.Taylor@leeds.ac.uk