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Phys. Rev. Lett. 101, 116602 (2008) [4 pages]

Visualizing the Spin of Individual Cobalt-Phthalocyanine Molecules

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C. Iacovita1, M. V. Rastei1, B. W. Heinrich1, T. Brumme2, J. Kortus2, L. Limot1,*, and J. P. Bucher1
1Institut de Physique et Chimie des Matériaux de Strasbourg UMR 7504, Université Louis Pasteur, F-67034 Strasbourg, France
2Institut für Theoretische Physik, TU Bergakademie Freiberg, D-09599 Freiberg, Germany

Received 5 May 2008; published 12 September 2008

Low-temperature spin-polarized scanning tunneling microscopy is employed to study spin transport across single cobalt-phthalocyanine molecules adsorbed on well-characterized magnetic nanoleads. A spin-polarized electronic resonance is identified over the center of the molecule and exploited to spatially resolve stationary spin states. These states reflect two molecular spin orientations and, as established by density functional calculations, originate from a ferromagnetic molecule-lead exchange interaction.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.101.116602
DOI:
10.1103/PhysRevLett.101.116602
PACS:
72.25.−b, 73.20.At, 75.70.Rf, 85.65.+h

*limot@ipcms.u-strasbg.fr