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Phys. Rev. Lett. 104, 067402 (2010) [4 pages]

Scaling the Temperature-Dependent Boson Peak of Vitreous Silica with the High-Frequency Bulk Modulus Derived from Brillouin Scattering Data

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B. Rufflé1, S. Ayrinhac1, E. Courtens1, R. Vacher1, M. Foret1, A. Wischnewski2, and U. Buchenau2
1Laboratoire des Colloïdes, Verres et Nanomatériaux, UMR 5587 CNRS Université Montpellier II, F-34095 Montpellier Cedex 5, France
2Institut für Feskörperforschung, Forschungszentrum Jülich, Postfach 1913, D-52425 Jülich, Germany

Received 18 September 2009; published 11 February 2010

The position and strength of the boson peak in silica glass vary considerably with temperature T. Such variations cannot be explained solely with changes in the Debye energy. New Brillouin-scattering measurements are presented which allow determining the T dependence of unrelaxed acoustic velocities. Using a velocity based on the bulk modulus, scaling exponents are found which agree with the soft-potential model. The unrelaxed bulk modulus thus appears to be a good measure for the structural evolution of silica with T and to set the energy scale for the soft potentials.

© 2010 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.104.067402
DOI:
10.1103/PhysRevLett.104.067402
PACS:
78.55.Qr, 63.50.Lm, 78.35.+c, 78.70.Nx