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Phys. Rev. Lett. 104, 096402 (2010) [4 pages]

CeFePO: f-d Hybridization and Quenching of Superconductivity

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M. G. Holder1, A. Jesche2, P. Lombardo3, R. Hayn3, D. V. Vyalikh1, S. Danzenbächer1, K. Kummer1, C. Krellner2, C. Geibel2, Yu. Kucherenko4, T. K. Kim5, R. Follath6, S. L. Molodtsov1,7, and C. Laubschat1
1Institut für Festkörperphysik, Technische Universität Dresden, D-01062 Dresden, Germany
2Max-Planck-Institut für Chemische Physik fester Stoffe, D-01187 Dresden, Germany
3Institut Matériaux, Microélectronique et Nanosciences de Provence, Faculté St. Jérôme, 13397 Marseille, France
4Institute for Metal Physics, National Academy of Sciences of Ukraine, UA-03142 Kiev, Ukraine
5Institut für Festkörperforschung, IFW Dresden, D-01171 Dresden, Germany
6Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Elektronenspeicherring BESSY II, D-12489 Berlin, Germany
7European XFEL GmbH, D-22761 Hamburg, Germany

Received 8 December 2009; published 5 March 2010

As a homologue to the new, Fe-based type of high-temperature superconductors, the electronic structure of the heavy-fermion compound CeFePO was studied by means of angle-resolved resonant photoemission. It was experimentally found—and later on confirmed by local-density approximation (LDA) as well as dynamical mean-field theory (DMFT) calculations—that the Ce 4f states hybridize to the Fe 3d states of d3z2-r2 symmetry near the Fermi level that discloses their participation in the occurring electron-correlation phenomena and provides insight into mechanism of superconductivity in oxopnictides.

© 2010 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.104.096402
DOI:
10.1103/PhysRevLett.104.096402
PACS:
71.27.+a