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Phys. Rev. Lett. 108, 035701 (2012) [5 pages]

Geometrical Frustration and Static Correlations in a Simple Glass Former

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Benoit Charbonneau1, Patrick Charbonneau2,3, and Gilles Tarjus3
1Mathematics Department, St. Jerome’s University in the University of Waterloo, Waterloo, Ontario, Canada
2Departments of Chemistry and Physics, Duke University, Durham, North Carolina 27708, USA
3LPTMC, CNRS-UMR 7600, Université Pierre et Marie Curie, boîte 121, 4 Place Jussieu, 75005 Paris, France

Received 12 September 2011; published 18 January 2012

We study the geometrical frustration scenario of glass formation for simple hard-sphere models. We find that the dual picture in terms of defects brings little insight and no theoretical simplification for the understanding of the slowing down of relaxation, because of the strong frustration characterizing these systems. The possibility of a growing static length is furthermore found to be physically irrelevant in the regime that is accessible to computer simulations.

© 2012 American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.108.035701
DOI:
10.1103/PhysRevLett.108.035701
PACS:
64.70.Q-, 02.40.Dr, 61.20.Ja, 64.70.kj