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Phys. Rev. Lett. 29, 772–775 (1972)

Dominant Second-Order Dipole-Moment Contribution in the Infrared Absorption of III-V Compounds

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Christos Flytzanis*
Division of Engineering and Applied Physics, Harvard University, Cambridge, Massachusetts 02138

Received 22 May 1972; published in the issue dated 18 September 1972

It is shown that a relationship exists between the coefficient describing the infrared lattice absorption and the ionic contribution to the second-order electric susceptibility in a polar noncentrosymmetric crystal. By analyzing the available data of the latter it is concluded that two-phonon sidebands in the infrared absorption are due to the second-order dipole moment in all the III-V compounds and to the third-order potential in ZnO and CdS. Further, the magnitude of the integrated infrared absorption coefficient in a cubic homopolar IV-IV semiconductor is discussed.

© 1972 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.29.772
DOI:
10.1103/PhysRevLett.29.772
PACS:

*On leave from Laboratoire d'Optique Quantique, Université de Paris-Sud, Centre d'Orsay, 91-Orsay, France.