Phys. Rev. Lett. 57, 1773–1776 (1986)Local Modes in Anharmonic Solids and the Kondo ProblemReceived 9 June 1986; published in the issue dated 6 October 1986 The quantum theory of local modes in molecules is extended to few-dimensional solids such as polyacetylene. Local modes are found to be present below the phonon band no matter how weak the anharmonicity. The problem of the local mode interacting with a phonon background is reduced to a Bose variety of the Kondo problem. Based on this analogy, a theory is constructed of thermal dissociation of local modes and the generation of high local-mode quantum numbers through intense radiation. © 1986 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevLett.57.1773
DOI:
10.1103/PhysRevLett.57.1773
PACS:
78.30.Jw, 63.20.Pw, 64.10.+h
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