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Phys. Rev. Lett. 57, 1773–1776 (1986)

Local Modes in Anharmonic Solids and the Kondo Problem

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R. Bruinsma
Physics Department, University of California at Los Angeles, Los Angeles, California 90024

K. Maki
Physics Department, University of Southern California, Los Angeles, California 90089

J. Wheatley
Physics Department, University of California at Los Angeles, Los Angeles, California 90024
Los Alamos National Laboratory, Los Alamos, New Mexico 87545

Received 9 June 1986; published in the issue dated 6 October 1986

The quantum theory of local modes in molecules is extended to few-dimensional solids such as polyacetylene. Local modes are found to be present below the phonon band no matter how weak the anharmonicity. The problem of the local mode interacting with a phonon background is reduced to a Bose variety of the Kondo problem. Based on this analogy, a theory is constructed of thermal dissociation of local modes and the generation of high local-mode quantum numbers through intense radiation.

© 1986 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.57.1773
DOI:
10.1103/PhysRevLett.57.1773
PACS:
78.30.Jw, 63.20.Pw, 64.10.+h