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Phys. Rev. Lett. 61, 1851–1854 (1988)

Orientational Distribution Function in Nematic Tobacco-Mosaic-Virus Liquid Crystals Measured by X-Ray Diffraction

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R. Oldenbourg1, X. Wen1, R. B. Meyer1, and D. L. D. Caspar1,2
1The Martin Fisher School of Physics, Brandeis University, Waltham, Massachusetts 02254
2The Rosenstiel Basic Medical Sciences Research Center, Brandeis University, Waltham, Massachusetts 02254

Received 6 July 1988; published in the issue dated 17 October 1988

Orientational distributions of the rod-shaped tobacco-mosaic-virus particle in magnetically aligned nematic solutions (0.05M borate buffer, pH 8.5) were measured by analysis of the angular spread of x-ray diffraction patterns. We measured Gaussian orientational distributions with order parameters varying between 0.77 in a solution with coexisting nematic and isotropic phase, to 0.95 in the single-phase nematic solution at higher concentration. Our experimental results are in good agreement with model calculations based on a modified Onsager theory for suspensions of hard rods.

© 1988 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.61.1851
DOI:
10.1103/PhysRevLett.61.1851
PACS:
61.30.Gd, 61.10.-i, 61.30.Eb, 64.70.Md

See Also

Comment: Moshe Deutsch, X-Ray Determination of the Orientational Distribution Function of Rod-Shaped Particles, Phys. Rev. Lett. 64, 697 (1990).