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Phys. Rev. Lett. 67, 1266–1269 (1991)

Dynamical mechanism for the formation of metastable phases

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John Bechhoefer, Hartmut Löwen, and Laurette S. Tuckerman
Laboratoire de Physique, Ecole Normale Supérieure de Lyon, 69364 Lyon CEDEX 07, France

Received 21 March 1991; published in the issue dated 2 September 1991

Rapid temperature quenches have long been known to produce metastable thermodynamic phases. We study Landau-Ginzburg models of phase transitions for free energies having three local minima and show that metastable phases can be formed via a dynamic instability that splits the front separating the stable high- and low-temperature phases. Even though quenching may nucleate the stable phase, the splitting instability we discuss will favor the formation of the metastable phase.

© 1991 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.67.1266
DOI:
10.1103/PhysRevLett.67.1266
PACS:
64.60.My