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Phys. Rev. Lett. 67, 622–625 (1991)

Surface diffusion modes for Pt dimers and trimers on Pt(001)

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G. L. Kellogg and A. F. Voter
Sandia National Laboratories, Albuquerque, New Mexico 87185
Los Alamos National Laboratory, Los Alamos, New Mexico 87545

Received 10 April 1991; published in the issue dated 29 July 1991

Field-ion-microscope observations and molecular statics calculations using embedded-atom-method potentials have identified the surface diffusion modes for Pt dimers and trimers on Pt(001). Dimers migrate by a series of displacements involving exchange between one of the dimer atoms and a substrate atom and have a lower activation barrier for diffusion than monomers. Trimer diffusion involves both exchange and hopping displacements and has an activation barrier comparable to monomers.

© 1991 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.67.622
DOI:
10.1103/PhysRevLett.67.622
PACS:
61.16.Fk, 61.16.Fk, 66.30.Fq