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Phys. Rev. Lett. 72, 1814–1817 (1994)

Theoretical investigation of collisions of aligned atoms: Ca(4s4f 1F)+He

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A. P. Hickman, J. J. Portman, S. Krebs, and W. Meyer
Molecular Physics Laboratory, SRI International, Menlo Park, California 94025
Fakultät für Chemie, Universität Kaiserslautern, 67663 Kaiserslautern, Germany

Received 30 August 1993; published in the issue dated 21 March 1994

Cross sections for inelastic collisions of aligned, excited atoms are calculated using ab initio molecular potential curves and couplings and a fully quantum mechanical scattering treatment. Agreement with currently available data is reasonable. The cross sections for specific transitions exhibit strong, energy-dependent oscillations, which are attributed to an interference effect.

© 1994 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.72.1814
DOI:
10.1103/PhysRevLett.72.1814
PACS:
34.50.Pi