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Phys. Rev. Lett. 73, 1602–1604 (1994)

Random Copolymers with Short-Range Interaction in the Equilibrium State: Mean Field Approximation and Numerical Studies

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Michael Schulz
Department of Chemistry, University at Albany, State University of New York, Albany, New York 12222

Roland G. Winkler and Peter Reineker
Abteilungen für Theoretische Physik, Universität Ulm, 89069 Ulm, Germany

Received 8 April 1994; published in the issue dated 19 September 1994

We study macromolecules with quenched random charge disorder along the chain and short-range interactions between the monomers. Within a mean-field approach a collapse of a chain with increasing disorder is found, which becomes more pronounced for long chains. Molecular dynamics simulations reveal the same tendency, though the actual shape of the radius of gyration as a function of the disorder is different and reflects the finite length of a chain.

© 1994 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.73.1602
DOI:
10.1103/PhysRevLett.73.1602
PACS:
36.20.-r, 02.60.Cb, 05.70.Ce