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Phys. Rev. Lett. 74, 422–425 (1995)

Numerical Study of Phase Transitions in the Pores of an Aerogel

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Katarina Uzelac
Institute of Physics of the University, University of Zagreb, Bijenicka 46, POB 304, 41000 Zagreb, Croatia

Anwar Hasmy and Rémi Jullien
Laboratoire de Science des Matériaux Vitreux, Université Montpellier II, Place Eugène Bataillon, 34095 Montpellier, France

Received 10 June 1994; published in the issue dated 16 January 1995

An aerogel of volume fraction c is modeled on a 3D lattice using diffusion-limited cluster-cluster aggregation in cubic boxes of sizes up to 20 × 20 × 20. A set of q-state Potts variables are disposed on the nonoccupied sites and their order-disorder phase transition is studied by means of a Monte Carlo technique for q=3 and q=4. It is found that the transition changes from first to second order above a nonzero threshold value of c. A comparison is made with the case of randomly occupied sites. The possible application to recent experimental results is discussed.

© 1995 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.74.422
DOI:
10.1103/PhysRevLett.74.422
PACS:
64.60.Ak, 05.70.Fh, 75.40.Mg