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Phys. Rev. Lett. 81, 2160–2163 (1998)

Mechanism of Thickness Determination in Polymer Crystals

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Jonathan P. K. Doye and Daan Frenkel
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands.

Received 19 March 1998; published in the issue dated 7 September 1998

Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum thermodynamically stable thickness. This description contrasts with those given by the two dominant theoretical approaches.

© 1998 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.81.2160
DOI:
10.1103/PhysRevLett.81.2160
PACS:
81.10.Aj, 64.60.Qb, 68.45.Da