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Phys. Rev. Lett. 82, 2904–2907 (1999)

Dynamical Diffraction and X-Ray Standing Waves from Atomic Planes Normal to a Twofold Symmetry Axis of the Quasicrystal AlPdMn

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Terrence Jach1, Y. Zhang2, R. Colella2, M. de Boissieu3, M. Boudard3, A. I. Goldman4, T. A. Lograsso4, D. W. Delaney4, and S. Kycia5
1National Institute of Standards and Technology, Gaithersburg, Maryland 20899
2Department of Physics, Purdue University, West Lafayette, Indiana 47907
3LTPCM-ENSEEG, BP 75, 38402 St. Martin d'Hères Cédex, France
4Department of Physics and Ames Laboratory, Iowa State University, Ames, Iowa 50011
5CHESS, Cornell University, Ithaca, New York 14853

Received 28 August 1998; published in the issue dated 5 April 1999

We have observed dynamical diffraction in the [[(02402̅ 4) and [[(04604̅ 6) reflections of the icosahedral quasicrystal AlPdMn in the back-reflection geometry ( θB = 90°). The x-ray fluorescence from the Al and Pd atoms exhibits strong standing wave behavior, similar to that observed in crystalline materials. The data indicate a long-range order of each species of atoms, with the coherent positions attributable to distributions of the Al and Pd, which we compare to a centrosymmetric model. We observe deviations from the model which imply small departures from inversion symmetry along the twofold symmetry axis and from the expected coherent fractions for Al.

© 1999 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.82.2904
DOI:
10.1103/PhysRevLett.82.2904
PACS:
61.44.Br, 61.10.-i