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Phys. Rev. Lett. 82, 1181–1184 (1999)

Friction and Molecular Deformation in the Tensile Regime

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A. R. Burns, J. E. Houston, R. W. Carpick, and T. A. Michalske
Surface and Interface Sciences Department, MS 1413, Sandia National Laboratories, Albuquerque, New Mexico 87185-1413

Received 30 July 1998; published in the issue dated 8 February 1999

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Recent molecular level studies of energy dissipation in sliding friction have suggested a contribution from adhesive forces. In order to observe this directly, we have constructed a scanning force microscope with decoupled lateral and normal force sensors to simultaneously observe the onset of both friction and attractive forces. Measurements made on self-assembling alkanethiol films with chemically different tail groups show that friction can increase with stronger adhesive intermolecular forces and from the associated tensile deformation and collective motion of the thiol chains.

© 1999 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.82.1181
DOI:
10.1103/PhysRevLett.82.1181
PACS:
61.16.Ch, 07.79.Sp, 62.20.Qp, 81.40.Pq