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Phys. Rev. Lett. 83, 4622–4625 (1999)

Superconducting-Normal Phase Transition in (Ba1-xKx)BiO3, x = 0.40, 0.47

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B. F. Woodfield*, D. A. Wright, R. A. Fisher, and N. E. Phillips
Department of Chemistry, University of California and Lawrence Berkeley National Laboratory, Berkeley, California 94720

H. Y. Tang
Department of Applied Chemistry, National Chi Nan University, Puli, Nantou 545, Taiwan

Received 26 July 1999; published in the issue dated 29 November 1999

Specific-heat measurements on (Ba1-xKx)BiO3, x = 0.40 and 0.47, 0.7T35K, 0H9T, have determined the coefficient (γ) of the normal-state conduction electron specific heat, and shown well-defined specific-heat anomalies at Tc that are consistent with the value of γ and BCS expressions. These results contradict the suggestion in a recent Letter that γ is several orders of magnitude greater than these experimental values and that the absence of a correspondingly large specific-heat anomaly constitutes evidence that the transition is an Ehrenfest fourth-order transition.

© 1999 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.83.4622
DOI:
10.1103/PhysRevLett.83.4622
PACS:
74.25.Bt, 74.25.Ha, 74.62.Dh

*Present address: Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602.