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Phys. Rev. Lett. 83, 5185–5189 (1999)

Boson Correlation Energies from Reduced Hamiltonian Interpolation

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David A. Mazziotti1,2 and Dudley R. Herschbach2
1Department of Chemistry, Duke University, Durham, North Carolina 27708-0346
2Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138

Received 12 August 1999; published in the issue dated 20 December 1999

The ground-state energies of interacting bosons are computed beyond the mean-field approximation by a new method which we call reduced Hamiltonian interpolation (RHI). In this interpolation the N-particle Hamiltonian is represented through a sequence of p-particle expanded and reduced Hamiltonians that give upper and lower bounds on the true energy. A synthesis of ideas from N-representability and dimensional interpolation, the RHI interpolates over the number p of quasiparticles (equivalent to spatial dimension) to calculate the N-particle energy as the mean of close upper and lower bounds. Application to bosons with harmonic interactions yields more than 99% of the correlation energy.

© 1999 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.83.5185
DOI:
10.1103/PhysRevLett.83.5185
PACS:
02.60.Ed, 03.65.Ge, 05.30.Jp