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Phys. Rev. Lett. 84, 2742–2745 (2000)

Formation of Uniaxial Molecular Films by Liquid-Crystal Imprinting in a Magnetic Field

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Joseph D. Mougous, Andrew J. Brackley, Katherine Foland, Robert T. Baker, and David L. Patrick*
Department of Chemistry, Western Washington University, Bellingham, Washington 98225

Received 21 September 1999; published in the issue dated 20 March 2000

See accompanying Physics Focus

Scanning tunneling microscopy was used to study molecular order in monolayer organic films formed by solution-phase growth from thermotropic liquid crystal solvents. The films develop macroscopically uniaxial alignment, with adlayer orientation controlled by an external magnetic field through interactions mediated by the liquid crystal. Results are presented for two films deposited from nematic and smectic- A solvents, along with a discussion of the alignment mechanism.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.84.2742
DOI:
10.1103/PhysRevLett.84.2742
PACS:
83.70.Jr, 68.45.-v, 81.10.Dn

*To whom correspondence should be addressed.Email address: patrick@chem.wwu.edu