corner
corner

Phys. Rev. Lett. 84, 3454–3457 (2000)

Butterfly Hysteresis Loop and Dissipative Spin Reversal in the S = 1/2, V15 Molecular Complex

Download: PDF (150 kB) Buy this article Export: BibTeX or EndNote (RIS)

I. Chiorescu1,*, W. Wernsdorfer1, A. Müller2, H. Bögge2, and B. Barbara1
1Laboratoire de Magnétisme Louis Néel, CNRS, BP 166, 38042 Grenoble, France
2Fakültat für Chemie, Universität Bielefeld, D-33501 Bielefeld, Germany

Received 19 April 1999; published in the issue dated 10 April 2000

Time resolved magnetization measurements have been performed on a spin 1/2 molecular complex, so-called V15. Despite the absence of a barrier, magnetic hysteresis is observed over a time scale of several seconds. A detailed analysis in terms of a dissipative two-level model is given, in which fluctuations and splittings are of the same energy. Spin-phonon coupling leads to long relaxation times and to a particular “butterfly” hysteresis loop.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.84.3454
DOI:
10.1103/PhysRevLett.84.3454
PACS:
75.50.Xx, 71.70.-d, 75.45.+j

*Corresponding author. Electronic address: ichiores@polycnrs-gre.fr