corner
corner

Phys. Rev. Lett. 85, 2530–2532 (2000)

Solid Clusters above the Bulk Melting Point

Download: PDF (62 kB) Buy this article Export: BibTeX or EndNote (RIS)

Alexandre A. Shvartsburg and Martin F. Jarrold
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208

Received 31 March 2000; published in the issue dated 18 September 2000

See accompanying Physics Focus

The fact that the melting points of nanoparticles are always lower than those of the corresponding bulk material is a paradigm supported by extensive experimental data for a large number of systems and by numerous calculations. Here we demonstrate that tin cluster ions with 10–30 atoms remain solid at 50 K above the melting point of bulk tin. This behavior is possibly related to the fact that the structure of the clusters is completely different from that of the bulk element.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.85.2530
DOI:
10.1103/PhysRevLett.85.2530
PACS:
61.46.+w, 64.70.Dv