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Phys. Rev. Lett. 85, 3664–3667 (2000)

Observation of a Near-Surface Structural Phase Transition in SrTiO3 by Optical Second Harmonic Generation

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E. D. Mishina1, T. V. Misuryaev1, N. E. Sherstyuk1, V. V. Lemanov2, A. I. Morozov1, A. S. Sigov1, and Th. Rasing3
1Moscow Institute of Radioengineering, Electronics and Automation, Moscow 117454, Russia
2A.F. Ioffe Physical Technical Institute, 194021 St. Petersburg, Russia
3Research Institute for Materials, University of Nijmegen, Toernooiveld 1, NL-6525 ED Nijmegen, The Netherlands

Received 6 May 1999; revised 14 January 2000; published in the issue dated 23 October 2000

A near-surface structural phase transition on a SrTiO3 single crystal, occurring at T* about 45 K above the bulk cubic-to-tetragonal transition, is observed by means of optical second harmonic generation. The temperature dependence of the second harmonic field in the vicinity of T* is described with a phenomenological Landau-type model.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.85.3664
DOI:
10.1103/PhysRevLett.85.3664
PACS:
68.35.Rh, 42.65.Ky, 77.80.Bh