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Phys. Rev. Lett. 85, 5364–5367 (2000)

Electrical and Mechanical Properties of C70 Fullerene and Graphite under High Pressures Studied Using Designer Diamond Anvils

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Jeremy R. Patterson, Shane A. Catledge, and Yogesh K. Vohra
Department of Physics, University of Alabama at Birmingham (UAB), Birmingham, Alabama 35294-1170

Jagannadham Akella and Samuel T. Weir
Lawrence Livermore National Laboratory (LLNL), Livermore, California 94550

Received 24 August 2000; published in the issue dated 18 December 2000

We compare electrical and mechanical properties of C70 fullerene with high purity graphite to 48GPa at room temperature using designer diamond anvils with embedded electrical microprobes. The electrical resistance of C70 shows a minimum at 20GPa with transformation to an amorphous insulating phase complete above 35GPa, while graphite remains conducting. Nanoindentation shows hardness values 220 times larger for the pressure quenched amorphous phase than for similarly treated graphite. Our studies establish that the amorphous carbon phase produced from C70 has unique properties not attainable from graphite.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.85.5364
DOI:
10.1103/PhysRevLett.85.5364
PACS:
62.50.+p, 07.35.+k, 62.20.-x, 64.70.Kb