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Phys. Rev. Lett. 85, 980–983 (2000)

Direct Experimental Evidence of Slip in Hexadecane: Solid Interfaces

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R. Pit, H. Hervet, and L. Léger*
Laboratoire de Physique de la Matière Condensée, URA CNRS 792, Collège de France, 11 place Marcelin Berthelot, 75231 Paris Cedex 05, France

Received 27 December 1999; revised 4 May 2000; published in the issue dated 31 July 2000

The boundary condition for the flow velocity of a Newtonian fluid near a solid wall has been probed experimentally with a novel setup using total internal reflection–fluorescence recovery after photobleaching leading to a resolution from the wall of the order of 80 nm. For hexadecane flowing on a hydrocarbon/lyophobic smooth surface, we give what we think to be the first direct experimental evidence of noticeable slip at the wall. We show that the surface roughness and the strength of the fluid-surface interactions both act on wall slip, in antagonist ways.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.85.980
DOI:
10.1103/PhysRevLett.85.980
PACS:
47.27.Nz, 68.45.-v, 81.40.Pq

*To whom correspondence should be addressed.