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APS » Journals » Phys. Rev. Lett. » Volume 86 » Issue 26
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Phys. Rev. Lett. 86, 6030–6033 (2001)

Dislocation-Controlled Perforated Layer Phase in a PEO- b-PS Diblock Copolymer

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Lei Zhu1, Ping Huang1, Stephen Z. D. Cheng1,*, Qing Ge1, Roderic P. Quirk1, Edwin L. Thomas2, Bernard Lotz3, Jean-Claude Wittmann3, Benjamin S. Hsiao4, Fengji Yeh4, and Lizhi Liu4
1Maurice Morton Institute and Department of Polymer Science, The University of Akron, Akron, Ohio 44325-3909
2Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
3Institute Charles Sadron, 6 Rue Boussingault, Strasbourg 67083, France
4Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400

Received 8 March 2001; published in the issue dated 25 June 2001

Small angle x-ray analyses show that the shear-induced hexagonal perforated layer phase in a poly(ethylene oxide)- b-polystyrene diblock copolymer consists of trigonal ( R3̅ m) twins and a hexagonal ( P63/mmc) structure, with trigonal twins being majority components. Transmission electron microscopy reveals that the hexagonal structure is generated through sequential intrinsic stacking faults on the second layer from a previous edge dislocation line, while the trigonal twins are formed by successive intrinsic stacking faults on neighboring layers due to the plastic deformation under mechanical shear.

© 2001 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.86.6030
DOI:
10.1103/PhysRevLett.86.6030
PACS:
82.35.Jk, 61.72.Ff, 82.35.Lr, 83.80.Uv

*To whom correspondence should be addressed. Email address: cheng@polymer.uakron.edu

 
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