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Phys. Rev. Lett. 88, 155701 (2002) [4 pages]

Mobility Transition of Solid Rare Gases in Confined Environments

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D. E. Silva1, P. E. Sokol1, and S. N. Ehrlich2
1Department of Physics, The Pennsylvania State University, University Park, Pennsylvania 16802
2National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973

Received 14 June 2001; published 1 April 2002

We report the results of x-ray diffraction and small angle scattering studies of Ar and Kr confined in sol-gel and Vycor glasses. The confined liquid crystallizes in a disordered hcp structure on freezing. Upon further cooling a sharp transition occurs at a reduced temperature of T/Tm0.65, where the crystalline structure disappears and the total scattering decreases. This behavior marks the onset of a well-defined mobility transition, where the confined sample migrates out of the pore space.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.88.155701
DOI:
10.1103/PhysRevLett.88.155701
PACS:
64.70.Kb, 61.10.Eq, 61.43.Gt, 66.30.Hs