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Phys. Rev. Lett. 88, 168102 (2002) [4 pages]

Viscosity of Two-Dimensional Suspensions

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Junqi Ding, Heidi E. Warriner, and Joseph A. Zasadzinski*
Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080

Received 12 July 2001; published 8 April 2002

Over a range of conditions, lipid and surfactant monolayers exhibit coexistence of discrete solid domains in a continuous liquid. The surface shear viscosity, μs, of such monolayers collapses onto a single curve: μs/μso = [1-(A/Ac)]-1, in which μso is the viscosity of the liquid phase, A is the area fraction of the solid phase measured by fluorescence microscopy, and Ac is a critical solid phase fraction. This scaling relationship is directly analogous to that of three-dimensional dispersion of spheres in a solvent with long-range repulsive interactions, with area fraction replacing volume fraction.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.88.168102
DOI:
10.1103/PhysRevLett.88.168102
PACS:
68.18.-g, 82.70.Uv, 83.80.-k

*To whom correspondence should be directed. Email address: gorilla@engineering.ucsb.edu