Phys. Rev. Lett. 88, 195701 (2002) [4 pages]Interplay between Time-Temperature Transformation and the Liquid-Liquid Phase Transition in WaterReceived 6 February 2002; published 26 April 2002 We study the new water model proposed by Mahoney and Jorgensen [J. Chem. Phys. 112, 8910 (2000)], which is closer to real water than previously proposed classical pairwise additive potentials. We simulate the model in a wide range of deeply supercooled states and find (i) the existence of a nonmonotonic “nose-shaped” temperature of maximum density line and a nonreentrant spinodal, (ii) the presence of a low-temperature phase transition, (iii) the free evolution of bulk water to ice, and (iv) the time-temperature-transformation curves at different densities. © 2002 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevLett.88.195701
DOI:
10.1103/PhysRevLett.88.195701
PACS:
64.70.Ja, 02.70.Ns
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