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Phys. Rev. Lett. 89, 067601 (2002) [4 pages]

Observation of Nanoscale 180° Stripe Domains in Ferroelectric PbTiO3 Thin Films

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S. K. Streiffer1,*, J. A. Eastman1, D. D. Fong1, Carol Thompson2,1, A. Munkholm3, M. V. Ramana Murty1,†, O. Auciello1, G. R. Bai1, and G. B. Stephenson1
1Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439
2Physics Department, Northern Illinois University, DeKalb, Illinois 60115
3Lumileds Lighting, San Jose, California 95131

Received 27 March 2002; published 19 July 2002

We report the observation of periodic 180° stripe domains below the ferroelectric transition in thin films. Epitaxial PbTiO3 films of thickness d=1.6 to 42 nm on SrTiO3 substrates were studied using x-ray scattering. Upon cooling below TC, satellites appeared around Bragg peaks indicating the presence of 180° stripe domains of period Λ=3.7 to 24 nm. The dependence of Λ on d agrees well with theory including epitaxial strain effects, while the suppression of TC for thinner films is significantly larger than that expected solely from stripe domains.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.89.067601
DOI:
10.1103/PhysRevLett.89.067601
PACS:
77.80.Bh, 61.10.Eq, 64.70.Nd, 68.55.–a

*Electronic address: streiffer@anl.gov

Current address: E2O Communications Corp., 26679 W. Agoura Road, Calabasas, CA 91302.