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Phys. Rev. Lett. 90, 057401 (2003) [4 pages]

Optical Properties of Gold Nanorings

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J. Aizpurua1, P. Hanarp2, D. S. Sutherland2, M. Käll2, Garnett W. Bryant1, and F. J. García de Abajo3
1National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423
2Department of Applied Physics, Chalmers University of Technology, S-41296 Göteborg, Sweden
3Centro Mixto CSIC-UPV/EHU and Donostia International Physics Center (DIPC), Apartado 1072, 20080 San Sebastián, Spain

Received 13 August 2002; published 3 February 2003

The optical response of ring-shaped gold nanoparticles prepared by colloidal lithography is investigated. Compared to solid gold particles of similar size, nanorings exhibit a redshifted localized surface plasmon that can be tuned over an extended wavelength range by varying the ratio of the ring thickness to its radius. The measured wavelength variation is well reproduced by numerical calculations and interpreted as originating from coupling of dipolar modes at the inner and outer surfaces of the nanorings. The electric field associated with these plasmons exhibits uniform enhancement and polarization in the ring cavity, suggesting applications in near-infrared surface-enhanced spectroscopy and sensing.

© 2003 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.90.057401
DOI:
10.1103/PhysRevLett.90.057401
PACS:
78.67.Bf, 61.46.+w, 73.20.Mf