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Phys. Rev. Lett. 91, 115701 (2003) [4 pages]

Does the Arrhenius Temperature Dependence of the Johari-Goldstein Relaxation Persist above Tg?

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M. Paluch1, C. M. Roland2, S. Pawlus1, J. Zioło1, and K. L. Ngai2
1Institute of Physics, Silesian University, ul. Uniwersytecka 4, 40-007 Katowice, Poland
2Naval Research Laboratory, Chemistry Division, Code 6120, Washington, D.C. 20375-5342, USA

Received 4 April 2003; published 9 September 2003

Dielectric spectra of the polyalcohols sorbitol and xylitol were measured under isobaric pressures up to 1.8 GPa. At elevated pressure, the separation between the α and β relaxation peaks is larger than at ambient pressure, enabling the β relaxation times to be unambiguously determined. Taking advantage of this, we show that the Arrhenius temperature dependence of the β relaxation time does not persist for temperatures above Tg. This result, consistent with inferences drawn from dielectric relaxation measurements at ambient pressure, is obtained directly, without the usual problematic deconvolution the β and α processes.

© 2003 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.91.115701
DOI:
10.1103/PhysRevLett.91.115701
PACS:
64.70.Pf, 77.22.Gm