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Phys. Rev. Lett. 92, 105701 (2004) [4 pages]

Nearly Logarithmic Decay of Correlations in Glass-Forming Liquids

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W. Götze and M. Sperl
Physik-Department, Technische Universität München, 85747 Garching, Germany

Received 21 October 2003; published 9 March 2004

Nearly logarithmic decay of correlations, which was observed for several supercooled liquids in optical-Kerr-effect experiments [ G. Hinze et al. Phys. Rev. Lett. 84 2437 (2000); H. Cang et al. Phys. Rev. Lett. 90 197401 (2003)], is explained within the mode-coupling theory for ideal glass transitions as a manifestation of the β-peak phenomenon. A schematic model, which describes the dynamics by only two correlators, one referring to density fluctuations and the other to the reorientational fluctuations of the molecules, yields for strong rotation-translation coupling response functions in agreement with those measured for benzophenone and Salol for the time interval extending from 2 ps to about 20 and 200 ns, respectively.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.92.105701
DOI:
10.1103/PhysRevLett.92.105701
PACS:
64.70.Pf, 33.55.Fi, 61.20.Lc, 61.25.Em