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Phys. Rev. Lett. 92, 175504 (2004) [4 pages]

Driving Force of Stacking-Fault Formation in SiC p-i-n Diodes

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S. Ha and M. Skowronski
Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, USA

J. J. Sumakeris, M. J. Paisley, and M. K. Das
Cree, Inc., 4600 Silicon Drive, Durham, North Carolina 27703, USA

Received 24 November 2003; published 30 April 2004

The driving force of stacking-fault expansion in SiC p-i-n diodes was investigated using optical emission microscopy and transmission electron microscopy. The stacking-fault expansion and properties of the partial dislocations were inconsistent with any stress as the driving force. A thermodynamic free energy difference between the perfect and a faulted structure is suggested as a plausible driving force in the tested diodes, indicating that hexagonal polytypes of silicon carbide are metastable at room temperature.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.92.175504
DOI:
10.1103/PhysRevLett.92.175504
PACS:
61.72.Ff, 81.05.Hd, 85.30.Kk