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Phys. Rev. Lett. 92, 216802 (2004) [4 pages]

Variable Range Hopping Conduction in Semiconductor Nanocrystal Solids

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Dong Yu, Congjun Wang, Brian L. Wehrenberg, and Philippe Guyot-Sionnest
James Franck Institute, University of Chicago, Chicago, Illinois 60637, USA

Received 22 December 2003; published 25 May 2004

The temperature and electrical field dependent conductivity of n-type CdSe nanocrystal thin films is investigated. In the low electrical field regime, the conductivity follows σ∼exp⁡[-(T*/T)1/2] in the temperature range 10<T<120  K. At high electrical field, the conductivity is strongly field dependent. At 4 K, the conductance increases by 8 orders of magnitude over one decade of bias. At a very high field, conductivity is temperature independent with σ∼exp⁡[-(E*/E)1/2]. The complete behavior is very well described by variable range hopping with a Coulomb gap.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.92.216802
DOI:
10.1103/PhysRevLett.92.216802
PACS:
73.22.–f, 05.60.Cd, 73.50.Fq, 73.63.Kv