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Phys. Rev. Lett. 93, 117801 (2004) [4 pages]

Ordered Droplet Structures at the Liquid Crystal Surface and Elastic-Capillary Colloidal Interactions

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I. I. Smalyukh1, S. Chernyshuk2, B. I. Lev2,3, A. B. Nych2, U. Ognysta2, V. G. Nazarenko2, and O. D. Lavrentovich1,*
1Liquid Crystal Institute and Chemical Physics Interdisciplinary Program, Kent State University, Kent, Ohio 44242, USA
2Institute of Physics, Prospect Nauki 46, Kyiv-39, 03039, Ukraine
3Japan Science and Technology Corporation, Yokoyama Nano-structured Liquid Crystal Project, 5-9-9 Tokodai, Ibaraki 300-2635, Japan

Received 27 February 2004; published 8 September 2004

We demonstrate a variety of ordered patterns, including hexagonal structures and chains, formed by colloidal particles (droplets) at the free surface of a nematic liquid crystal (LC). The surface placement introduces a new type of particle interaction as compared to particles entirely in the LC bulk. Namely, director deformations caused by the particles lead to distortions of the interface and thus to capillary attraction. The elastic-capillary coupling is strong enough to remain relevant even at the micron-scale when its buoyancy-capillary counterpart becomes irrelevant.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.93.117801
DOI:
10.1103/PhysRevLett.93.117801
PACS:
61.30.–v, 68.03.Cd, 82.70.Kj, 89.75.Fb

*Corresponding author

Electronic address: odl@lci.kent.edu