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Phys. Rev. Lett. 93, 055701 (2004) [4 pages]

Equilibrium Cluster Phases and Low-Density Arrested Disordered States: The Role of Short-Range Attraction and Long-Range Repulsion

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Francesco Sciortino1, Stefano Mossa1,2, Emanuela Zaccarelli1, and Piero Tartaglia1
1Dipartimento di Fisica and INFM Udr and Center for Statistical Mechanics and Complexity, Università di Roma “La Sapienza,” Piazzale Aldo Moro 2, I-00185, Roma, Italy
2European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble CEDEX, France

Received 13 February 2004; published 29 July 2004

We study a model in which particles interact with short-ranged attractive and long-ranged repulsive interactions, in an attempt to model the equilibrium cluster phase recently discovered in sterically stabilized colloidal systems in the presence of depletion interactions. At low packing fractions, particles form stable equilibrium clusters which act as building blocks of a cluster fluid. We study the possibility that cluster fluids generate a low-density disordered arrested phase, a gel, via a glass transition driven by the repulsive interaction. In this model the gel formation is formally described with the same physics of the glass formation.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.93.055701
DOI:
10.1103/PhysRevLett.93.055701
PACS:
64.70.Pf, 61.20.Lc