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Phys. Rev. Lett. 94, 126103 (2005) [4 pages]

Very Low Friction State of a Dodecane Film Confined between Mica Surfaces

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A. Jabbarzadeh1, Peter Harrowell2, and R. I. Tanner1
1School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, New South Wales 2006, Australia
2School of Chemistry, The University of Sydney, New South Wales 2006, Australia

Received 21 September 2004; published 1 April 2005

The existence of a very low friction state of a lubrication film is demonstrated in nonequilibrium molecular dynamics simulations of a six-layer dodecane film between mica walls. We argue that this low friction state is thermodynamically stable with respect to the well documented high friction film, the latter being a metastable state. These results are in striking accord with the recent report of Zhu and Granick [ Phys. Rev. Lett. 93 096101 (2004)]. The extreme low friction is the result, not of wall slip, but of layer sliding throughout the film, a mechanism similar to solid lubrication.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.94.126103
DOI:
10.1103/PhysRevLett.94.126103
PACS:
68.35.Af, 81.40.Pq