corner
corner

Phys. Rev. Lett. 94, 145504 (2005) [4 pages]

Real-Time Evolution of the Distribution of Nanoparticles in an Ultrathin-Polymer-Film-Based Waveguide

Download: PDF (870 kB) Buy this article Export: BibTeX or EndNote (RIS)

Suresh Narayanan1, Dong Ryeol Lee1, Rodney S. Guico1,2, Sunil K. Sinha3, and Jin Wang1
1Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA
2Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, USA
3Department of Physics, University of California, La Jolla, California 92093, USA and Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Received 13 October 2004; published 15 April 2005

We report a novel application of an ultrathin-polymer-film-based, resonance-enhanced x-ray waveguide as a real-time nanoprobe for elucidating dilute, yet disordered, gold nanoparticles embedded in the polymer matrix. This nanoprobe promises a sensitivity enhancement of several orders of magnitude, hence revealing in real time the lateral nanoparticle distribution with subnanometer spatial resolution. We observed that the motion of the nanoparticles is strongly anisotropic, with in-plane coalescence taking place more rapidly than out-of-plane diffusion, which can ultimately facilitate the formation of two-dimensional structures.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.94.145504
DOI:
10.1103/PhysRevLett.94.145504
PACS:
61.10.Eq, 66.10.Cb, 81.07.-b, 82.35.Np