Phys. Rev. Lett. 94, 157002 (2005) [4 pages]Evidence for Charge Kondo Effect in Superconducting Tl-Doped PbTeReceived 9 September 2004; published 21 April 2005 We report results of low-temperature thermodynamic and transport measurements of Pb1-xTlxTe single crystals for Tl concentrations up to the solubility limit of approximately x=1.5%. For all doped samples, we observe a low-temperature resistivity upturn that scales in magnitude with the Tl concentration. The temperature and field dependence of this upturn are consistent with a charge Kondo effect involving degenerate Tl valence states differing by two electrons, with a characteristic Kondo temperature TK∼6 K. The observation of such an effect supports an electronic pairing mechanism for superconductivity in this material and may account for the anomalously high Tc values. © 2005 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevLett.94.157002
DOI:
10.1103/PhysRevLett.94.157002
PACS:
74.70.Dd, 72.15.Qm
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