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Phys. Rev. Lett. 94, 185502 (2005) [4 pages]

Melting of Dense Sodium

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Eugene Gregoryanz1, Olga Degtyareva1, Maddury Somayazulu2, Russell J. Hemley1, and Ho-kwang Mao1
1Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Road N.W., Washington D.C. 20015, USA
2HPCAT, Carnegie Institution of Washington, Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, USA

Received 26 January 2005; published 13 May 2005

High-pressure high-temperature synchrotron diffraction measurements reveal a maximum on the melting curve of Na in the bcc phase at ∼31  GPa and 1000 K and a steep decrease in melting temperature in its fcc phase. The results extend the melting curve by an order of magnitude up to 130 GPa. Above 103 GPa, Na crystallizes in a sequence of phases with complex structures with unusually low melting temperatures, reaching 300 K at 118 GPa, and an increased melting temperature is observed with further increases in pressure.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.94.185502
DOI:
10.1103/PhysRevLett.94.185502
PACS:
61.10.Nz, 61.20.Ne, 62.50.+p, 64.70.Dv