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Phys. Rev. Lett. 94, 197602 (2005) [4 pages]

Mobile High Resolution Xenon Nuclear Magnetic Resonance Spectroscopy in the Earth’s Magnetic Field

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Stephan Appelt1,*, F. Wolfgang Häsing1, Holger Kühn2, Juan Perlo2, and Bernhard Blümich2
1Zentralinstitut für Elektronik, Forschungszentrum Jülich, D-52425 Jülich, Germany
2Institut für Technische Chemie und Makromolekulare Chemie, RWTH Aachen, D-52056 Aachen, Germany

Received 26 January 2005; published 17 May 2005

Conventional high resolution nuclear magnetic resonance (NMR) spectra are usually measured in homogeneous, high magnetic fields (>1  T), which are produced by expensive and immobile superconducting magnets. We show that chemically resolved xenon (Xe) NMR spectroscopy of liquid samples can be measured in the Earth’s magnetic field (∼5×10-5  T) with a continuous flow of hyperpolarized Xe gas. It was found that the measured normalized Xe frequency shifts are significantly modified by the Xe polarization density, which causes different dipolar magnetic fields in the liquid and in the gas phases.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.94.197602
DOI:
10.1103/PhysRevLett.94.197602
PACS:
76.60.-k, 07.55.Ge, 32.80.Bx

*To whom all correspondence should be addressed. Electronic address: st.appelt@fz-juelich.de