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Phys. Rev. Lett. 95, 130604 (2005) [4 pages]

Structural Order for One-Scale and Two-Scale Potentials

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Zhenyu Yan1, Sergey V. Buldyrev2,1, Nicolas Giovambattista3, and H. Eugene Stanley1
1Center for Polymer Studies and Department of Physics, Boston University, Boston, Massachusetts 02215, USA
2Department of Physics, Yeshiva University, 500 West 185th Street, New York, New York 10033, USA
3Department of Chemical Engineering, Princeton University, Princeton, New Jersey 08544-5263, USA

Received 26 May 2005; published 22 September 2005

We perform molecular dynamics simulations to investigate the relationship between structural order and waterlike dynamic and thermodynamic anomalies in spherically symmetric potentials having either one or two characteristic length scales. Structural order is characterized by translational and orientational order parameters. We find that (i) dynamic and thermodynamic anomalies exist for both one-scale and two-scale ramp potentials, and (ii) waterlike structural order anomalies exist only for the two-scale ramp potential. Our findings suggest that the waterlike relationship between structural order and anomalies is related to the presence of two different length scales in the potential.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.95.130604
DOI:
10.1103/PhysRevLett.95.130604
PACS:
05.20.Jj, 61.20.−p