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Phys. Rev. Lett. 95, 097201 (2005) [4 pages]

Irradiation-Induced Magnetism in Carbon Nanostructures

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S. Talapatra1,2,*, P. G. Ganesan1, T. Kim1, R. Vajtai2, M. Huang3, M. Shima1, G. Ramanath1,2, D. Srivastava4, S. C. Deevi5, and P. M. Ajayan1,2
1Department of MS & E, Rensselaer Polytechnic Institute, Troy, New York 12180-3590, USA
2Rensselaer Nanotechnology Center, Rensselaer Polytechnic Institute, Troy, New York 12180-3590, USA
3Department of Physics, SUNY Albany, New York 12203, USA
4NASA Ames Research Center, Moffett Field, California 94035, USA
5RD & E Center, Phillip Morris USA, Richmond, Virginia 23234, USA

Received 20 April 2005; published 23 August 2005

Nitrogen (15N) and carbon (12C) ion implantations with implant energy of 100 keV for different doses were performed on nanosized diamond (ND) particles. Magnetic measurements on the doped ND show ferromagnetic hysteresis behavior at room temperature. The saturation magnetization (Ms) in the case of 15N implanted samples was found to be higher compared to the 12C implanted samples for dose sizes greater than 1014  cm-2. The role of structural modification or defects along with the carbon-nitrogen (C-N) bonding states for the observed enhanced ferromagnetic ordering in 15N doped samples is explained on the basis of x-ray photoelectron spectroscopy measurements.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.95.097201
DOI:
10.1103/PhysRevLett.95.097201
PACS:
75.75.+a, 72.80.Ng, 75.50.Pp

*Electronic address: talaps@rpi.edu