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Phys. Rev. Lett. 96, 236102 (2006) [4 pages]

Velocity Dependence of Friction and Hydrogen Bonding Effects

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Jinyu Chen, Imma Ratera, Jeong Young Park, and Miquel Salmeron*
Materials Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley California 94720, USA

Received 1 February 2006; published 15 June 2006

We show that the friction force varies with the sliding velocity in a manner that depends on the chemical nature of the interface. Surfaces terminated with the hydrogen acceptor and donor moieties capable of forming H-bond networks exhibit a friction that decreases with sliding velocity, a behavior that is opposite to that of surfaces where no such networks can form. We explain the results with a model where the domains of glassy H-bond networks are disrupted at a critical applied stress leading to slippage.

© 2006 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.96.236102
DOI:
10.1103/PhysRevLett.96.236102
PACS:
68.35.Af, 62.20.Qp, 62.25.+g, 68.37.Ps

*To whom all correspondence should be addressed.

Electronic address: mbsalmeron@lbl.gov