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Phys. Rev. Lett. 97, 255902 (2006) [4 pages]

Atomistic Mechanism of Boron Diffusion in Silicon

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Davide De Salvador1,*, Enrico Napolitani1, Salvatore Mirabella2, Gabriele Bisognin1, Giuliana Impellizzeri2, Alberto Carnera1, and Francesco Priolo2
1MATIS INFM-CNR and Padova University, Physics Department, via Marzolo 8, 35131 Padova, Italy
2MATIS INFM-CNR and Catania University, Physics and Astronomy Department, via S. Sofia 64, 95123 Catania, Italy

Received 8 August 2006; published 20 December 2006

B diffuses in crystalline Si by reacting with a Si self-interstitial (I) with a frequency g and so forming a fast migrating BI complex that can migrate for an average length λ. We experimentally demonstrate that both g and λ strongly depend on the free hole concentration p. At low p, g has a constant trend and λ increases with p, while at high p, g has a superlinear trend and λ decreases with p. This demonstrates that BI forms in the two regimes by interaction with neutral and double positive I, respectively, and its charge state has to change by interaction with free holes before diffusing.

© 2006 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.97.255902
DOI:
10.1103/PhysRevLett.97.255902
PACS:
66.30.Jt, 61.72.Ji, 68.49.Sf, 85.40.Ry

*Electronic address: desalvador@padova.infm.it