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Phys. Rev. Lett. 98, 147402 (2007) [4 pages]

Dielectric Response of Aligned Semiconducting Single-Wall Nanotubes

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J. A. Fagan1,*, J. R. Simpson1, B. J. Landi2, L. J. Richter1, I. Mandelbaum1, V. Bajpai1, D. L. Ho1, R. Raffaelle2, A. R. Hight Walker1, B. J. Bauer1, and E. K. Hobbie1,†
1National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
2NanoPower Research Laboratories, Rochester Institute of Technology, Rochester, New York 14623, USA

Received 25 October 2006; published 6 April 2007

We report measurements of the full intrinsic optical anisotropy of isolated single-wall carbon nanotubes (SWNTs). By combining absorption spectroscopy with transmission ellipsometry and polarization-dependent resonant Raman scattering, we obtain the real and imaginary parts of the SWNT permittivity from aligned semiconducting SWNTs dispersed in stretched polymer films. Our results are in agreement with theoretical predictions, highlighting the limited polarizability of excitons in a quasi-1D system.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.98.147402
DOI:
10.1103/PhysRevLett.98.147402
PACS:
78.67.Ch, 77.22.−d, 78.20.Ci

*Email address: jfagan@nist.gov

Email address: erik.hobbie@nist.gov