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Phys. Rev. Lett. 98, 096106 (2007) [4 pages]

How Pb-Overlayer Islands Move Fast Enough to Self-Assemble on Pb-Cu Surface Alloys

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M. L. Anderson1, N. C. Bartelt2, P. J. Feibelman1, B. S. Swartzentruber1, and G. L. Kellogg1
1Sandia National Laboratories, Albuquerque, New Mexico 87185, USA
2Sandia National Laboratories, Livermore, California 94550, USA

Received 31 October 2006; published 2 March 2007

Low-energy electron microscopy reveals that two-dimensional, ∼50 000 atom, Pb-overlayer and vacancy islands both have diffusion coefficients of 25.6±0.8  nm2/sec⁡ at 400 °C on Pb-Cu surface alloys. This high mobility, key to self-assembly in this system, results from the fast transport of Pb atoms on the surface alloy and of Cu through the Pb overlayer. A high Pb vacancy concentration, predicted by ab initio calculations, facilitates the latter.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevLett.98.096106
DOI:
10.1103/PhysRevLett.98.096106
PACS:
68.35.Fx, 68.37.Nq, 68.43.Jk, 81.16.Dn